Journal
CHEMCATCHEM
Volume 9, Issue 24, Pages 4460-4464Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.201700986
Keywords
boron; hydrosilanes; oxides; reaction mechanisms; reduction
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Funding
- Centre National de la Recherche Scientifique (CNRS)
- Conseil Regional de Normandie
- European FEDER
- Normandie Universite, Labex Synorg [ANR-11-LABX-0029]
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The general reduction of phosphine oxides, sulfoxides, and amine N-oxides was achieved by combining bis(2-chlorophenyl)borinic acid with phenylsilane. The reaction was shown to tolerate a wide range of substrates and could be performed under mild conditions, with only 2.5 mol% of the easily synthesized catalyst. Mechanistic investigations pointed to a key borohydride as the real catalyst and at bis(2-chlorophenyl)borinic acid as a precatalyst.
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