Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 56, Issue 50, Pages 15950-15953Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201708514
Keywords
crystallography; hybrid perovskites; phase transitions; Prussian blues; thermal expansion
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Materials in the family of Prussian blue analogues (C3H5N2)(2)K[M(CN)(6)], where C3H5N2 is the imidazolium ion and M=Fe, Co, undergo two phase transitions with temperature; at low temperatures the imidazolium cations have an ordered configuration (C2/c), while in the intermediate- and high-temperature phases (both previously reported as R (3) over barm) they are dynamically disordered. We show from high-resolution powder neutron diffraction data that the high-temperature phase has zero area thermal expansion in the ab-plane. Supported by Landau theory and single-crystal X-ray diffraction data, we re-evaluate the space group symmetry of the intermediate- temperature phase to R (3) over bar. This reveals that the low-to-intermediate temperature transition is due to competition between two different tilt patterns of the [M(CN)(6)](3-) ions. Controlling the relative stabilities of these tilt patterns offers a potential means to tune the exploitable electric behaviour that arises from motion of the imidazolium guest.
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