Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 56, Issue 50, Pages 15936-15940Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201706564
Keywords
electron transfer; energy conversion; molecular dyads; photosynthesis; time-resolved spectroscopy
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Funding
- LabEx PALM [ANR-10-LABX-0039-PALM]
- IDI project - IDEX Paris-Saclay [ANR-11-IDEX-003-02]
- IRS-MOMENTOM
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Biomimetic models that contain elements of photosynthesis are fundamental in the development of synthetic systems that can use sunlight to produce fuel. The critical task consists of running several rounds of light-induced charge separation, which is required to accumulate enough redox equivalents at the catalytic sites for the target chemistry to occur. Long-lived first charge-separated state and distinct electronic signatures for the sequential charge accumulated species are essential features to be able to track these events on a spectroscopic ground. Herein, we use a double-excitation nanosecond pump-pump-probe experiment to interrogate two successive rounds of photo-induced electron transfer on a molecular dyad containing a naphthalene diimide (NDI) linked to a [Ru(bpy)(3)](2+) (bpy=bipyridine) chromophore by using a reversible electron donor. We report an unprecedented long-lived two-electron charge accumulation (t=200s).
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