Journal
CHEMCATCHEM
Volume 9, Issue 23, Pages 4319-4323Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.201700965
Keywords
crystallization; hydroformylation; rhodium; ruthenium; tandem catalysis
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Funding
- German Science Foundation [SFB/TRR 63]
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An orthogonal tandem catalytic system consisting of rhodium and ruthenium complexes yielded linear C-12 ,-bifunctional compounds from commercial, castor oil derived renewable substrates. With aldehyde yields up to 88% and selectivities to the linear species of up to 95%, this approach is direct and atom economic and provides easy access to potential polymer precursors for polycondensates. Additionally, a straightforward method for selective product crystallization was developed, which enabled recycling of the tandem catalytic system for two runs with excellent activity and simultaneously provided a high-purity product.
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