Journal
TETRAHEDRON LETTERS
Volume 58, Issue 13, Pages 1308-1311Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2017.02.046
Keywords
Enaminones; Pyrimidones; Trifluoromethyl sulfides; Trifluoromethyl sulfoxides; Ttrifluoromethyl sulfones
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Methyl 3-(dimethylamino) acrylates containing trifluoromethylsulfenyl-, trifluoromethylsulfinyl-, and trifluoromethylsulfonyl groups were synthesized and their utility demonstrated by reactions with aliphatic and aromatic amidines to produce 2,5 -substituted 4(3H)-pyrimidones. Cyclization reactions of enaminones with urea or thiourea led to 5 -substituted uracil or 2-thiouracil derivatives, respectively. (C) 2017 Elsevier Ltd. All rights reserved.
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