Journal
TETRAHEDRON LETTERS
Volume 58, Issue 22, Pages 2162-2165Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2017.04.075
Keywords
MIDA boronates; Photoredox catalysis; Perfluorohaloalkanes; ATRA
Categories
Funding
- Warsaw University of Technology
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The development of a visible light-mediated atom transfer radical addition (ATRA) of perfluoroalkyl iodides to ethynyl-, vinyl- and allyl-MIDA boronates using the reductive and oxidative quenching of [Ru(bPY)(3)]Cl-2 is described. Using an operationally simple and mild protocol, the corresponding MIDA boronates containing perfluoroalkyl groups were obtained in moderate to high yields. The structures of three products were confirmed by single crystal X-ray diffraction studies. (C) 2017 Elsevier Ltd. All rights reserved.
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