Journal
TETRAHEDRON LETTERS
Volume 58, Issue 23, Pages 2294-2297Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2017.04.099
Keywords
Biphasic electrolysis; Electrochemical; Quinone; Dialcohol; Phenol; Naphthol
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Electrochemical synthesis of quinones has been attempted from phenols, 1,4-dihydroxybenzenes, 1,4-dihydroxynaphthalenes and related compounds using biphasic media. Excellent yields of quinones (98%) or brominated diols have been achieved with good current efficiency. Reuse of the electrolyte without any modification and quantitative conversion of substrate with theoretical amount of current are the advantages of this method. (C) 2017 Elsevier Ltd. All rights reserved.
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