Journal
TETRAHEDRON LETTERS
Volume 58, Issue 21, Pages 2058-2061Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2017.04.042
Keywords
Electron-deficient alkenes; Hydroxyphosphorylation; beta-Hydroxyphosphine oxide; Copper catalysis; Dioxygen
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Funding
- Chinese National Natural Science Foundation [21402184, 21572217, 21302109]
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A copper-catalyzed direct hydroxyphosphorylation of electron-deficient alkenes with H-phosphine oxides and dioxygen is reported. The present reaction, proceeds under mild reaction conditions with good functional group tolerance, affording the facile and efficient synthesis of various beta-hydroxyphosphine oxides in a scaled-up manner with moderate to good yields. (C) 2017 Elsevier Ltd. All rights reserved.
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