Journal
TETRAHEDRON
Volume 73, Issue 27-28, Pages 3979-3985Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2017.05.077
Keywords
Multicomponent; Microwave-assisted synthesis; Imino-NH-1,2,3-triazoles; Trimethylsilyl(triethylgermyl) propynals; Metal-free 1,3-dipolar cycloaddition
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Funding
- Russian Foundation for Basic Research [15-03-99566a]
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Highly efficient microwave-assisted solvent- and catalyst-free multicomponent synthesis of 5-R-imino[4-trialkylsilyl(germyl)]-1H-1,2,3-triazoles from Si/Ge-substituted propynals, trimethylsilyl azide and functionalized primary amines has been developed. In the case of 2-aminoethanethiol, 4-element substituted 5-(1,3-thiazolan-2-yl)-1H-1,2,3-triazoles have been obtained. Their heterolysis by MeOH at room temperature leads to the corresponding triazoloimines in high yield. (C) 2017 Elsevier Ltd. All rights reserved.
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