Journal
TETRAHEDRON
Volume 73, Issue 31, Pages 4602-4609Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2017.06.028
Keywords
Chan-Evans-Lam couplings; Phosphinamides; Phosphonamides; Copper diacetate; Arylboronic acids
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Funding
- National Natural Science Foundation of China [21072052]
- National Basic Research Program of China [2009CB421601]
- Hunan Provincial Science and Technology Department Program [2011WK4007, 06FJ4115]
- Fundamental Research Funds for the Central Universities
- Hunan University [531107040840]
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A stoichiometric copper(II)-mediated arylation protocol of phosphinamides and phosphonamides was herein demonstrated. Various unreported N-aryl phosphinamides and phosphonamides were successfully prepared through Chan-Evans-Lam reaction with high efficiency (up to 88% yields) and good functional groups tolerance (30 examples) in the absence of any ligands or co-catalysts. (C) 2017 Elsevier Ltd. All rights reserved.
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