Journal
TETRAHEDRON
Volume 73, Issue 26, Pages 3591-3595Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2017.03.055
Keywords
Arylation; Rhodium; Phenol; Diaryliodonium salts; Biaryls
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Funding
- National Natural Science Foundation of China [21402096, 21421062, 21672107]
- Cutting-edge Technology Research Plan [14JCYBJC41400]
- Tianjin Applied Basic Research Project
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Rh-catalyzed ortho-selective arylation of free phenol with diaryliodonium triflates to widely existed phenol-containing biaryls have been developed. The use of P(NMe2)(3), (BuOLi)-Bu-t and CH3CN proved to be critical for the ortho-selectivity of this reaction. (C) 2017 Elsevier Ltd. All rights reserved.
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