4.6 Article

Cp*CoIII-Catalyzed Bis-isoquinolone Synthesis by C-H Annulation of Arylamide with 1,3-Diyne

Journal

CHEMISTRY-A EUROPEAN JOURNAL
Volume 23, Issue 69, Pages 17454-17457

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201704155

Keywords

annulation; cobalt(III); heterocycles; internal oxidant; isoquinolone

Funding

  1. SERB [EMR2016/000136]
  2. IITK
  3. CSIR

Ask authors/readers for more resources

Cp*Co-III-catalyzed highly regioselective mono- and bis-annulation of arylamides with 1,3-diynes using N-OMe as an internal oxidant is demonstrated. This atom-economical transformation does not require any external oxidant and tolerates many functional groups. Various symmetrical and unsymmetrical heterocycles (homo and hetero) are accessed with predictable regio- and chemoselectivity.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.6
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

No Data Available
No Data Available