Journal
ACS OMEGA
Volume 2, Issue 10, Pages 7066-7070Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acsomega.7b01248
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Funding
- JAIST
- Chulalongkorn University
- JSPS-KAKENHI [17H03455, 17H04966]
- Grants-in-Aid for Scientific Research [17H03455, 17H04966] Funding Source: KAKEN
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Au nanoparticles supported on alumina (Au/Al2O3) with average particle size of 3.9 +/- 0.7 nm and surface plasmon band centerned at 516.5 nm were prepared by deposition-precipitation method, and their photocatalytic activities for the reduction of nitrobenzene using either formic acid in acetonitrile (method A) or KOH in 2-propanol (method B) were investigated. Even at room temperature, the Au/Al2O3 was found to be highly active and selective for conversion of nitrobenzene to aniline when used with formic acid in acetonitrile or to azobenzene when performed with KOH in 2-propanol under irradiation with green light-emitting diode (517 nm).
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