4.7 Article

A single molecular fluorescent probe for selective and sensitive detection of nitroaromatic explosives: A new strategy for the mask-free discrimination of TNT and TNP within same sample

Journal

TALANTA
Volume 166, Issue -, Pages 228-233

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.talanta.2017.01.046

Keywords

Naphthalene; Fluorescence; Dual sensing; TNT detection; TNP detection; DFT calculations

Funding

  1. National Natural Science Foundation of China [21507005]
  2. Excellent Young Scholar Research Found of Beijing Institute of Technology of China [3090012331542]

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A simple naphthalene based fluorescent probe was first time reported as dual sensing of 2,4,6-trinitrotolune (TNT) and 2,4,6-trinitrophenol (TNP) by distinguishable changes in both solution color change and fluorescence within same sample without any mask agent. Upon addition of TNT and TNP, the strong emission quenching at 412 nm and a new emission band at 530 nm was observed, respectively. In addition, the sensing mechanism was evaluated by DFT calculations by Gaussian 09 software.

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