Journal
ACS OMEGA
Volume 2, Issue 9, Pages 6278-6290Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acsomega.7b01111
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Funding
- Science and Engineering Research Board [EMR/2015/000043]
- Council of Scientific and Industrial Research [02(0255)/16/EMR-II]
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Metal-free dioxygenation of alkenes with tertbutyl nitrite and N-hydroxylamines (N-hydroxyphthalimide, N-hydroxybenzotriazole, and N-hydroxysuccinimide) is described to produce beta-aminoxy nitrate esters using air as the oxidant. These organic nitrates can be readily converted into 1,2-diols and 1,2-diketone with broad substrate scope and functional group diversity.
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