Journal
TALANTA
Volume 171, Issue -, Pages 242-249Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.talanta.2017.05.006
Keywords
Bisphenol A; Molecularly imprinted polymer; Ultrasound assisted emulsification micro-solid phase extraction; High performance liquid chromatography; Aqueous matrices
Categories
Funding
- Ministry of Education Malaysia [304.CIPPT.6313197, 203.CIPPT.6711484]
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Molecularly imprinted polymer (MIP) was employed as sorbent in ultrasound assisted emulsification molecularly imprinted polymer micro-solid phase extraction (USAE-MIP-mu-SPE) of bisphenol A (BPA) in water, beverages and the aqueous liquid in canned foods prior to high performance liquid chromatography diode array detector (HPLC-DAD) analysis. Several effective variables, such as types of emulsification solvent and its volume, types of desorption solvent and its volume, salting out effect, pH of sample solution, mass of sorbent, extraction and desorption time, and sample volume, were optimized comprehensively. Under the optimized USAE-MIP-mu-SPE and HPLC-DAD conditions, the method demonstrated good linearity over the range of 0.5-700 mu g L-1 with a coefficient determination of R-2=0.9973, low limit of detection (0.07 mu g L-1), good analyte recoveries (82.2-118.9%) and acceptable RSDs (0.7-14.2%, n=3) with enrichment factor of 49. The method was applied to thirty samples of drinking water, mineral water, river water, lake water, as well as beverages and canned foods, the presence of BPA was identified in four samples. The proposed method showed good selectivity and reusability for extraction of BPA, and hence the USAE-MIP-mu-SPE is rapid, simple, cost effective and environmentally friendly.
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