Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 56, Issue 51, Pages 16367-16370Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201710053
Keywords
aryl halides; carbenes; cobalt; N-heterocycles; Suzuki coupling
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Funding
- Commonwealth Scholarship Commission
- EPSRC
- Engineering and Physical Sciences Research Council [EP/K012258/1, EP/K03927X/1] Funding Source: researchfish
- EPSRC [EP/K012258/1, 1794061, EP/K03927X/1] Funding Source: UKRI
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Readily accessed cobalt pre-catalysts with N-hetero-cycliccarbene ligands catalyze the Suzuki cross-coupling of aryl chlorides and bromides with alkyllithium-activated arylboronic pinacolate esters. Preliminary mechanistic studies indicate that the cobalt species is reduced to Co-0 during the reaction.
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