Journal
SYNTHESIS-STUTTGART
Volume 49, Issue 14, Pages 3035-3068Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0036-1589021
Keywords
donor-acceptor cyclopropanes; nucleophilic ring opening; N-nucleophiles; N-heterocycles; amines; azides; nitriles
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Ring opening of donor-acceptor cyclopropanes with various N-nucleophiles provides a simple approach to 1,3-functionalized compounds that are useful building blocks in organic synthesis, especially in assembling various N-heterocycles, including natural products. In this review, ring-opening reactions of donor-acceptor cyclopropanes with amines, amides, hydrazines, N-heterocycles, nitriles, and the azide ion are summarized.
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