Journal
SYNTHESIS-STUTTGART
Volume 49, Issue 8, Pages 1707-1745Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0036-1589482
Keywords
organobismuth compounds; hypervalency; chirality; arylation reactions; cross-coupling reactions; metal-catalyzed reactions
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Funding
- Natural Sciences and Engineering Research Council of Canada (NSERC)
- Universite du Quebec a Montreal (UQAM)
- Centre in Green Chemistry and Catalysis (CGCC)
- Fonds de Recherche Nature et Technologies (FRQNT)
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Organobismuth compounds are organometallic reagents that contain a C- Bi bond. These species, which are easily accessed from inexpensive and low- toxicity inorganic bismuth salts, are highly attractive in synthesis due to their unique properties and reactivity. A wide diversity of geometries have been found for organobismuth compounds, depending on the oxidation state of the bismuth, its charge, and the number of coordinated elements. Compounds where the bismuth bears a - 1 charge (organobismuthate), a + 1 (bismuthonium cation) and a + 2 charge (bismuthonium dication) have been reported. Due to the presence of a lone pair, trivalent organobismuthines can act as Lewis bases in transition- metal complexes. In addition, organobismuth compounds can act as Lewis acids by forming hypervalent interactions with ligands and metals. Organobismuth compounds have been used as catalysts and reagents in a plethora of reactions. In this review, the synthesis and properties of organobismuth reagents and their use in organic reactions are reviewed.
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