4.5 Article

Indium-Catalyzed Direct Conversion of Lactones into Thiolactones and Selenolactones in the Presence of Elemental Sulfur and Selenium

Journal

SYNTHESIS-STUTTGART
Volume 50, Issue 3, Pages 565-574

Publisher

GEORG THIEME VERLAG KG
DOI: 10.1055/s-0036-1591849

Keywords

thiolactone; selenolactone; lactone; indium; hydrosilane

Funding

  1. JSPS KAKENHI [JP25410120]

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The direct conversion of lactones into thiolactones with elemental sulfur (S-8) catalyzed by InCl3/PhSiH3 in a one-pot reaction is described. This catalytic system was successfully applied to the novel preparation of selenolactones from lactones and selenium.

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