Journal
SYNTHESIS-STUTTGART
Volume 50, Issue 1, Pages 119-126Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0036-1590892
Keywords
decarbonylation; dehalogenation; palladium catalyst; maghemite; magnetically recoverable catalyst
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Funding
- Ministry of Education, Science and Technological Development of Serbia [172008, III45004]
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A facile decarbonylation reaction of a variety of aromatic and heteroaromatic aldehydes using maghemite-supported palladium catalyst has been developed. The magnetic properties of catalyst facilitated an easy and efficient recovery of the catalyst from the reaction mixture using an external magnet. It was found that the catalyst could be reused up to four consecutive catalytic runs without a significant change in activity. In addition, the catalyst was also very effective in the dehalogenation of aryl halides. This is the first report on efficient utilization of directly immobilized Pd on maghemite in decarbonylation and dehalogenation reactions.
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