Journal
SYNTHESIS-STUTTGART
Volume 49, Issue 21, Pages 4769-4774Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0036-1588848
Keywords
borylation; diaryl sulfoxide; C-S cleavage; palladium; diboron
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Funding
- JSPS [JP16H01019, JP16H01149, JP16H04109, JP16H06887]
- ACT-C, JST
- Japan Association for Chemical Innovation
- Tokuyama Science Foundation
- The Naito Foundation
- Grants-in-Aid for Scientific Research [16H06887, 16H04109, 16H01019, 16H01149] Funding Source: KAKEN
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Borylation of the C-S bond of diaryl sulfoxides with bis(pinacolato)diboron (B(2)pin(2)) is accomplished by means of a phosphine-ligated palladium catalyst and LiN(SiMe3)(2) as a base. Both of the aryl rings of the diaryl sulfoxides are converted into borylated products.
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