Journal
SYNTHESIS-STUTTGART
Volume 49, Issue 16, Pages 3633-3642Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0036-1589022
Keywords
thioetherification; diarylmethyl thioethers; diaryl; carbinols; high atom economy; Lewis acid activator
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Funding
- UGC (Delhi)
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A waste-free and swift protocol to synthesize symmetrical and unsymmetrical diarylmethyl thioethers from diaryl carbinols and thiols in good to quantitative yields is reported. The thiol scope included alkyl and aryl thiols bearing electron-donating and electron-withdrawing groups. Short reaction time, high atom economy, inexpensive activator, free from workup and aryl halides, and gram-scale synthesis are the significant features of the new protocol.
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