Journal
SYNLETT
Volume 28, Issue 20, Pages 2795-2799Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0036-1590865
Keywords
spent nuclear fuel; BTPhen ligand; magnetic nanoparticles; solid-phase extraction; benzylic halogenation
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Funding
- UK Engineering and Physical Sciences Research Council [EP/M026485/1]
- Grant Agency of the Czech Technical University in Prague [SGS15/216/OHK4/3T/14]
- Engineering and Physical Sciences Research Council [EP/M026485/1, EP/M026396/1] Funding Source: researchfish
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Bis-(1,2,4-triazin-3-yl)-1,10-phenanthroline (BTPhen) functionalized magnetic nanoparticles (MNPs), which selectively extract Am(III) over europium(III) from 0.1 M HNO3 with fast kinetics and a separation factor of 30 have been synthesized. These MNPs also show a small but significant selectivity for Am(III) over Cm(III) with a separation factor of around 3 in 0.1 M HNO3 . We report also the synthesis of these BTPhen and related ligands via an improved synthetic route bypassing the problematic benzylic oxidation with stoichiometric SeO (2) .
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