Journal
SYNLETT
Volume 29, Issue 1, Pages 57-64Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0036-1588538
Keywords
cyclohexadienones; arylation; tandem reaction; aromatization; aza-Michael reaction; aryl heterocycles
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Cyclohexa-2,4-dien-1-one derivatives, upon reaction with N-heterocycles in the presence of scandium(III) triflate, underwent a tandem Michael addition reaction followed by aromatization of the Michael adduct generated in situ to give N-aryl heterocycles in good yields. Because of the ready accessibility of variously substituted cyclohexa-2,4-dien-1-ones, a range of N-aryl heterocycles have become available.
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