Journal
SYNLETT
Volume 29, Issue 10, Pages 1307-1313Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0036-1591841
Keywords
catalysis; DFT calculations; halogen bonding; kinetics; solvent effects
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Funding
- Fonds der Chemischen Industrie (Liebig scholarship)
- Fonds der Chemischen Industrie (Ph.D. scholarships)
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Extending earlier studies on iodine catalysis, experimental investigations show that various halogen-bond donors can also be employed to accelerate the Michael addition between trans -crotonophenone and indole. Solvent as well as counteranion effects have been analyzed, and kinetic and computational investigations provide additional insights into the mode of activation.
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