Journal
SYNLETT
Volume 29, Issue 6, Pages 754-758Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0036-1589117
Keywords
palladium; cyclobutenols; arylation; ring opening; ketones; cross-coupling; condensation; homogeneous catalysis
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Funding
- Grants-in-Aid for Scientific Research [16K05783] Funding Source: KAKEN
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A palladium(0)-catalyzed ring-opening cross-coupling reaction between tert-cyclobutenols and aryl halides produces gamma-arylated beta,gamma-unsaturated ketones. In the case of aryl halides bearing functional groups at the ortho position, the resulting ring-opened ketones undergo intramolecular condensation to afford bicyclic aromatic compounds.
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