4.4 Article

Oxidative Biaryl Coupling of N-Aryl Anilines by Using a Hypervalent Iodine(III) Reagent

Journal

SYNLETT
Volume 28, Issue 20, Pages 2941-2945

Publisher

GEORG THIEME VERLAG KG
DOI: 10.1055/s-0036-1590875

Keywords

biaryl diamines; hypervalent iodine; oxidative coupling

Funding

  1. Japan Society for the Promotion of Science (JSPS)
  2. Ministry of Education, Culture, Sports, Science and Technology (MEXT)
  3. Ritsumeikan Global Innovation Research Organization (R-GIRO) project
  4. JSPS
  5. Asahi Glass Foundation
  6. Grants-in-Aid for Scientific Research [17K08230, 16K08186] Funding Source: KAKEN

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Biaryl diamines are important building blocks in organic synthesis. Consequently, it is desirable to develop a general and mild synthetic approach to diverse biaryl diamines. Oxidative coupling is an efficient and promising strategy for the synthesis of these targets. We have now developed a direct formation of biaryl diamines by oxidative coupling using a hypervalent iodine(III) reagent.

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