Journal
SUPRAMOLECULAR CHEMISTRY
Volume 30, Issue 10, Pages 858-868Publisher
TAYLOR & FRANCIS LTD
DOI: 10.1080/10610278.2017.1406093
Keywords
Helicate; cage; spin-crossover; spin-transition
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Despite the intense interest in helicate and cage supramolecular architectures, only a small fraction of these are known to switch their spin-state in response to a stimulus, such as temperature and light. However, these have recently emerged as a promising new class of spin-crossover materials and although there are still relatively few examples, it is an active area of research. This review discusses the lessons learned and challenges associated with the design and study of spin-crossover helicates and cages before highlighting new developments in the field. [GRAPHICS] .
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