Journal
BATTERIES-BASEL
Volume 3, Issue 4, Pages -Publisher
MDPI
DOI: 10.3390/batteries3040035
Keywords
metal hydride (MH); nickel/metal hydride (Ni/MH) battery; hydrogen-absorbing alloy; electrochemistry; superlattice alloy
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High-power cylindrical nickel metal/hydride batteries using a misch metal-based Al-free superlattice alloy with a composition of La11.3Pr1.7Nd5.1Mg4.5Ni63.6Co13.6Zr0.2 were fabricated and evaluated against those using a standard AB(5) metal hydride alloy. At room temperature, cells made with the superlattice alloy showed a 40% lower internal resistance and a 59% lower surface charge-transfer resistance compared to cells made with the AB(5) alloy. At a low temperature (-10 degrees C), cells made with the superlattice alloy demonstrated an 18% lower internal resistance and a 60% lower surface charge-transfer resistance compared to cells made with the AB(5) alloy. Cells made with the superlattice alloy exhibited a better charge retention at -10 degrees C. A cycle life comparison in a regular cell configuration indicated that the Al-free superlattice alloy contributes to a shorter cycle life as a result of the pulverization from the lattice expansion of the main phase.
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