Interfacial modification of the electron collecting layer of low-temperature solution-processed organometallic halide photovoltaic cells using an amorphous perylenediimide

The efficiency of organometallic halide photovoltaic cells can be improved by interfacial modification of the titanium oxide (TiOx) electron collecting layer by a thin layer of an organic material. Enhancements of power conversion efficiency up to 37% were obtained with PC61BM, but the performance is highly dependent on processing conditions and PCBM is still an expensive material. Herein, a glass-forming perylenetetracarboxylicdiimide derivative (PDI-glass) was used as interface material. The devices were optimized with varying PDI-glass thickness. With an optimal 10 nm-thickness, a power conversion efficiency increase of 39% were obtained, with an increase in short-circuit current from 9.7 to 11.05 mA cm(-2) and fill factor from 0.51 to 0.61. Aside from the thickness of the PDI-glass layer, the process yields consistent results independent of the processing conditions. Photoluminescence spectra revealed the presence of charge transfer at the PDI-glass - active layer interface. The films were further studied by X-ray diffraction (XRD), atomic force microscopy (AFM), and scanning electron microscopy (SEM).