Novel Principles and Nanostructuring Methods for Enhanced Thermoelectrics

Thermoelectrics (TE), the direct solid-state conversion of waste heat to electricity, is a promising field with potential wide-scale application for power generation. Intrinsic conflicts in the requirements for high electrical conductivity but (a) low thermal conductivity and (b) a large Seebeck coefficient have made enhancing TE performance difficult. Several recent striking advances in the field are reviewed. In regard to the former conflict, notable bottom-up nanostructuring methods for phonon-selective scattering are discovered, namely using nanosheets, dislocations, and most strikingly a process to fabricate nano-micropores leading to a 100% enhancement in the figure of merit (ZT approximate to 1.6) for rare-earth-free skutterudites. Porous materials are hitherto considered as having poor TE performance, so this is a new paradigm. In regard to the latter conflict, nanocomposite materials with hybrid effects and use of magnetism are emerging as novel bottom-up methods to enhance TE. Material informatics efforts to identify high-ZT materials are also reviewed.