4.8 Article

Significantly Increased Solubility of Carbon Nanotubes in Superacid by Oxidation and Their Assembly into High-Performance Fibers

Journal

SMALL
Volume 13, Issue 38, Pages -

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/smll.201701131

Keywords

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Funding

  1. Korea Institute of Science and Technology (KIST) Open Research Program (ORP)
  2. Industrial Fundamental Technology Development Program - Ministry of Trade, Industry and Energy (MOTIE) [10052838]
  3. Nano Material Technology Development Program through the National Research Foundation (NRF) - Ministry of Science, ICT and Future Planning (MSIP) [2016M3A7B4905619]
  4. Ministry of Science & ICT (MSIT), Republic of Korea [2E27240] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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This study demonstrates that small amount of oxygen incorporated into carbon nanotubes (CNTs) during the purification process greatly increases their solubility in chlorosulfonic acid (CSA). Using as-purchased and unpurified CNT powders, the optimal purification process is established to significantly increase the solubility of CNTs in CSA, and spin CNT fibers with high mechanical strength (0.84 N tex(-1)) and electrical conductivity (1.4 MS m(-1)) from the CNT liquid crystal dope with high concentration of CNTs in CSA. The knowledge obtained here may guide development of a way to dissolve extremely long CNTs at high concentration and thereby to enable production of CNT fibers with ultimate properties.

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