Journal
SOLID OXIDE FUEL CELLS 15 (SOFC-XV)
Volume 78, Issue 1, Pages 3049-3064Publisher
ELECTROCHEMICAL SOC INC
DOI: 10.1149/07801.3049ecst
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Funding
- project Synfuel from Innovation Fund Denmark [4106-00006B]
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The effects of long-term operation in electrolysis mode on the microstructure of Ni/YSZ electrodes were investigated. The electrode structures were investigated in as reduced state and after 9000 h of operation in a 25 cell stack. Microstructural data were obtained by scanning electron microscopy and focused-ion-beam serial sectioning. Microstructural characteristics were extracted by 1D and 3D methods. Significant microstructural changes were observed between the two cells analyzed. A significant loss of Ni in the active electrode is observed, from similar to 29% (by volume) in the reference cell to similar to 24% as well as a coarsening of the Ni particle sizes. The long-term tested cell shows lower percolating triple phase boundary density (0.76 mu m/mu m(3)) than the un-tested reference (2.0 mu m/mu m(3)). This reduction is mainly due to the loss of triple phase boundary percolation through the Ni phase where a reduction from a percolation degree above 90% to similar to 50% is observed.
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