Journal
SEPARATION AND PURIFICATION TECHNOLOGY
Volume 182, Issue -, Pages 144-150Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.seppur.2017.03.047
Keywords
NZVI/TiO2 nano-tube arrays; Photoelectrode; Visible light photocatalysis; 4-Chlorphenol
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Funding
- National Natural Science Foundation of China [51508254]
- Nature Science Foundation of Gansu Province of China [1506RJZA216]
- Fundamental Research Funds for the Central Universities [lzujbky-2015-137]
- Opening Project of State Key Laboratory of High Performance Ceramics and Superfine Microstructure [SKL201509SIC]
- Open fund by Jiangsu Engineering Technology Research Center of Environmental Cleaning Materials [KFK1502]
- Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
- Key Laboratory of Comprehensive and Highly Efficient Utilization of Salt Lake Resources, Qinghai Institute of Salt Lake, Chinese Academy of Sciences
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In this study, nano-scale zero-valent iron (NZVI) decorated TiO2 nano-tube arrays (NZVI/TiO2 NTAs) photoelectrode was fabricated through anodization process, followed by galvanostatic electrodeposition strategy. Afterwards, physicochemical properties of the resulting NZVI/TiO2 NTAs samples were systematically studied by SEM, XRD, XPS, IJV vis DRS and photoelectrochemical (PECH) measurements. Results indicated that NZVI/TiO2 NTAs photoelectrode exhibited greatly enhanced visible light absorbance and high photogenerated charge separation efficiency. However, after photocatalytic (PC) reaction, NVZI particles were converted to alpha-Fe2O3 species, which would further improve the visible light absorbance and PC efficiency, which was confirmed by the further enhanced visible light PC performance for decomposition of 4-chlorphenol (4-CP) and generation of.OH radicals. Furthermore, the enhanced visible light mechanism of NZVI/TiO2 NTAs photoelectrode was detailed discussed. This study provides a versatile strategy to fabricate high-efficient catalysts which could be used in the high-toxic and refractory micro-pollutants elimination in water body. (C) 2017 Elsevier B.V. All rights reserved.
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