Journal
SENSORS AND ACTUATORS B-CHEMICAL
Volume 251, Issue -, Pages 951-957Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.snb.2017.05.102
Keywords
Rhodamine; Colorimetric; Fluorescent; DFT study; Turn on; Reversible
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We describe a new naked eye and fluorescent chemosensor which exhibited greater selectivity and specificity toward Cr3+ and Fe3+ ions over other tested metal ions. The newly synthesized compound, RBCB displayed a visual color change and fluorescence enhancement with Cr3+ and Fe3+ ions. Structural characterization of the title compound was carried out by FTIR, NMR and mass spectral analysis. Interaction of RBCB to Fe3+ and Cr3+ leads to spirolactum ring opening of rhodamine which inturn evokes a 56 and 25-fold fluorescence enhancement. For RBCB, the limit of detection even lower than the permissible [Cr3+] or [Fe3+] in drinking water as per WHO standard. The low RSD % and high recoveries demonstrate that RBCB can serve as a potential sensor for the accurate detection of Cr3+ and Fe3+ in real samples. DFT, FTIR and Mass spectral studies reveal that RBCB binds to Cr3+ and Fe3+ in a 1:1 pattern evidenced by Job's plot analysis. Furthermore, the sensor is insensitive to pH 6-10 therefore can be applied for environmental and biological samples. Moreover, titration experiments against sodium-EDTA revealed that the test compound can be used as reversible probe for Cr3+ and Fe3+ ions. (C) 2017 Elsevier B.V. All rights reserved.
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