Journal
SENSORS AND ACTUATORS B-CHEMICAL
Volume 240, Issue -, Pages 288-296Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.snb.2016.08.168
Keywords
Fluorescent sensor; Phenothiazine; Cyanide; Nucleophilic addition; Detection limit
Funding
- King Abdulaziz City for Science and Technology (KACST), Saudi Arabia [AT/35/159]
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A new phenothiazine derivative containing two dicyano-vinyl groups as the cyanide receptor on both sides was synthesized and fully characterized. The chemosensor showed an intramolecular charge transfer (ICT) absorption band at 494 nm and emission band at 633 nm in acetonitrile solution. Upon titration with different concentrations of cyanide anion both absorption and emission bands decreases in a ratio metric manner. This optical response for cyanide anion is due to the nucleophilic Michael addition of CN-on the alpha-position of the dicyano-vinyl groups present in the chemosensor in both sides and thus converting these electron acceptors to anionic electron donors and consequently breaking the conjugation, which ultimately affect the ICT and the fluorescence of the chemosensor. The result indicated that the chemosensor showed high sensitivity with a fast response of less than 50 s and selectivity toward cyanide anion with a detection limit as low as 3.2 x 10(-9) M, which is the lowest ever reported. The chemosensor reaction mechanism with CN- was studied by H-1 NMR and C-13 NMR, FTIR and mass spectroscopies. (C) 2016 Elsevier B.V. All rights reserved.
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