Journal
DYES AND PIGMENTS
Volume 136, Issue -, Pages 31-45Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.dyepig.2016.08.032
Keywords
Fused ring pyrazine; Acidochromism; Solvatochromism; Structure-property relationship; Multi-linear regression analysis; Density function theory
Funding
- University Grants Commission (UGC), India
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Donor-pi-acceptor-pi-auxiliary acceptor type compounds have been designed and synthesized to study their rigidity and structural effects on optical properties. Structural variation is achieved by changing the central pi-conjugated core with naphthalene, acenaphthene and phenanthrene based donor-pi-acceptor compounds containing N, N-diethyl aniline or morpholine as donor and pyrazine ring fused with phenanthroline as acceptor. A detailed study of positive and negative acidochromism is performed. Intramolecular charge transfer, solvatochromism and highly polar excited state of these compounds are elucidated by Lippert-Mataga, Mac-Rae and Reichardt correlations. Multilinear regression analysis using Kamlet-Taft and Catalan parameters is also performed to support the observed solvatochromism in absorption and emission spectra from non-polar to polar solvents. All the spectroscopic results were correlated theoretically by Density Functional Theory (DFT) computations. (C) 2016 Elsevier Ltd. All rights reserved.
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