4.7 Article

Superelastic and micaceous deformation in the intermetallic compound CaFe2As2

Journal

SCRIPTA MATERIALIA
Volume 141, Issue -, Pages 10-14

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.scriptamat.2017.07.008

Keywords

Plasticity; Superelasticity; Intermetallic compound; Micropillar compression; Density functional theory

Funding

  1. UConn Research Excellence Program
  2. NASA's Space Technology Research [NNX16AR60G]
  3. Colorado State University
  4. FEI Company under an FEI-UConn
  5. U.S. Department of Energy, Office of Basic Energy Science, Division of Materials Sciences and Engineering
  6. U.S Department of Energy by Iowa State University [DE-AC02-07CH11358]

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Single-crystalline intermetallic compound CaFe2As2 are known to exhibit both superelasticity and micaceous plasticity, but these phenomena have not been studied in detail. Here we report a study of the elastic and plastic deformation behaviors for CaFe2As2 single crystals grown in Sn-flux solution. The anisotropic mechanical response has been studied using micropillar compression tests performed in-situ within a scanning electron microscope. These data are compared with density functional, theory calculations to develop an understanding of micaceous plasticity in terms of strongly anisotropic generalized stacking fault energies. The results of this work will offer design guidelines to produce mechanically robust superelaStic structures. (C) 2017 Acta Materialia Inc, Published by Elsevier Ltd, All rights reserved.

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