Journal
BIORESOURCES
Volume 12, Issue 3, Pages 4515-4526Publisher
NORTH CAROLINA STATE UNIV DEPT WOOD & PAPER SCI
DOI: 10.15376/biores.12.3.4515-4526
Keywords
Aqueous ionic liquid; Tetra-n-butylphosphonium hydroxide; Softwood; Lignin; Cellulose; Multi-sample analysis
Categories
Funding
- Science and Technology Research Promotion Program for Agriculture, Forestry, Fisheries, and Food Industry [26052A]
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The wood dissolution properties of tetra-n-butylphosphonium hydroxide ([P-4,P-4,P-4,P-4]OH) were investigated. Cedar wood meal was treated with several concentrations of aqueous (aq.) [P-4,P-4,P-4,P-4]OH with hydrogen peroxide (H2O2) in a glass tube at 121 degrees C. The solution of 60% aq. [P-4,P-4,P-4,P-4]OH with H2O2 at 121 degrees C showed the best dissolution capability for woody biomass with a high dissolution rate of 0.152 g min(-1). Under this condition, 98.5% of the woody biomass, including both lignin and holocellulose, was dissolved after 3 h of treatment. The molecular weight distribution of lignin in the soluble fraction of the [P-4,P-4,P-4,P-4]OH mixtures was determined via size exclusion chromatography, and its weight-average molecular weight decreased from approximately 7500 g/mole after 0.5 h to 2 h of treatment to 5700 g/mole after 3 h and 2500 g/mole after 5 h of treatment. Lower molecular weight components were determined by high-performance liquid chromatography, and vanillin and vanillic acid were identified. The dissolved cellulose was precipitated, and its polymerization degree decreased significantly after 0.5 h of treatment compared to that of the original cellulose.
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