Journal
CHEMSUSCHEM
Volume 11, Issue 1, Pages 229-236Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cssc.201701696
Keywords
ionic liquids; lithium-oxygen batteries; temperature dependence; iron-doped zinc oxide; conversion-alloying anode
Funding
- BMW AG
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The room-temperature molten salt mixture of N,N-diethyl-N-(2-methoxyethyl)-N-methylammonium bis(trifluoromethanesulfonyl) imide ([DEME][TFSI]) and lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) salt is herein reported as electrolyte for application in Li-O-2 batteries. The [DEME][TFSI]-LiTFSI solution is studied in terms of ionic conductivity, viscosity, electrochemical stability, and compatibility with lithium metal at 30 degrees C, 40 degrees C, and 60 degrees C. The electrolyte shows suitable properties for application in Li-O-2 battery, allowing a reversible, low-polarization discharge-charge performance with a capacity of about 13Ahg in the positive electrode and coulombic efficiency approaching 100%. The reversibility of the oxygen reduction reaction (ORR)/oxygen evolution reaction (OER) is demonstrated by exsitu XRD and SEM studies. Furthermore, the study of the cycling behavior of the Li-O-2 cell using the [DEME][TFSI]-LiTFSI electrolyte at increasing temperatures (from 30 to 60 degrees C) evidences enhanced energy efficiency together with morphology changes of the deposited species at the working electrode. In addition, the use of carbon-coated Zn0.9Fe0.1O (TMO-C) lithium-conversion anode in an ionic-liquid-based Li-ion/oxygen configuration is preliminarily demonstrated.
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