4.4 Article

THERMOPHYSICAL PROPERTIES OF DIMETHYL ETHER/ATHABASCA BITUMEN SYSTEM

Journal

CANADIAN JOURNAL OF CHEMICAL ENGINEERING
Volume 96, Issue 2, Pages 597-604

Publisher

WILEY
DOI: 10.1002/cjce.23009

Keywords

bitumen; dimethyl ether; phase behaviour; equation of state; solvent-aided thermal recovery

Funding

  1. BP Canada Energy Group ULC
  2. Brion Energy
  3. N-Solv
  4. ConocoPhillips Canada
  5. Devon Canada Co.
  6. Foundation CMG
  7. Husky Energy
  8. Japan Canada Oil Sands Limited
  9. Nexen Energy ULC
  10. Cenovus
  11. Natural Sciences and Engineering Research Council of Canada (NSERC)
  12. Imperial Oil Limited
  13. PennWest Energy
  14. Statoil Canada Ltd.
  15. Suncor Energy
  16. Total EP Canada
  17. Department of Chemical and Petroleum Engineering at the University of Calgary
  18. Schulich School of Engineering at the University of Calgary

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Solvent-aided thermal recovery processes have recently gained practical and research interests among other thermal recovery methods due to their reduced environmental footprint and superior energy efficiency. One of the main challenges in design of solvent-based methods is selection of an appropriate solvent that maximizes the bitumen and solvent recoveries. This study attempts to introduce dimethyl ether (DME) as a non-conventional solvent for heavy oil and bitumen recovery. To investigate the performance of the proposed solvent, thermophysical properties of DME/bitumen are studied. Vapour-liquid equilibrium measurements including solubility, density, and viscosity are performed at three temperatures (100, 125, and 150 degrees C) and pressures up to 6 MPa. The results were compared with propane/bitumen and butane/bitumen systems. All the measured properties fall between propane and butane systems. The solubility and density data were fairly represented using PR-EoS with AARDs of 10.3 and 1.43 %, respectively, and viscosity data were correlated applying the Pederson corresponding state model with an AARD of 10.7 %. The results suggest that DME is a suitable substitute for solvents such as propane and butane in solvent-aided thermal recovery of bitumen from oil sands.

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