Journal
AICHE JOURNAL
Volume 64, Issue 2, Pages 538-549Publisher
WILEY
DOI: 10.1002/aic.15937
Keywords
Fenton-like catalyst; Cu-embedded alumina; dynamic structure; RhB degradation; hydroxyl radicals; kinetics
Categories
Funding
- National Science Foundation [21576084, U1463205, 91534127]
- International Cooperation Project of Shanghai Ministry of Science and Technology [14230710700]
- Chinese Education Ministry 111 project [B08021]
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Cu-embedded mesoporous alumina, as a Fenton-like catalyst prepared via a sol-gel method, showed excellent activity and durability for the degradation of refectory compounds. The origin of active sites for the generation of hydroxyl radicals (center dot OH) were thoroughly studied using multitechniques. Cu, as the only active element, could be penetrated into the bulk of alumina and some Cu atoms were embedded into the framework. The dynamic structure of surface Cu species (the variety of Cu+/Cu2+ ratio) during the reaction were determined as well. Furthermore, the structure plasticity of catalyst has proved by optimizing preparation and reaction conditions. A 98.53% degradation of RhB was recorded within 30 min, following a pseudo-first-order reaction rate expression. Electron spin resonance spectra and center dot OH scavenging experiments have confirmed that center dot OH is the main reactive oxidant for the elimination of RhB. By the surface-enhanced Raman spectroscopy and gas chromatography-mass spectrometer results, plausible pathways of RhB degradation were elaborated. (c) 2017 American Institute of Chemical Engineers AIChE J, 64: 538-549, 2018
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