4.8 Article

Spectroscopic Evidence for Ligand Substitution Reactions at the Solid-Liquid Interface of a Sub-micrometer Gold(I) Carbene Complex

Journal

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 57, Issue 3, Pages 663-667

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201708945

Keywords

colloids; gold; halide ligands; heterogeneous reactions; multiphase systems

Funding

  1. International Visegrad Fund/V4EaP Scholarship Program [51601208]
  2. National Science Center (NCN, Poland) [UMO - 2015/16/W/ST5/00005]
  3. Erasmus+ Program-European Region Action Scheme for the Mobility of University Students

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Colloidal coordination compounds in the sub-micrometer range were synthesized from a chloro gold(I) carbene complex via the anti-solvent procedure and stabilized by a surfactant shell of Tween 20. This compound was successfully applied as model system to monitor heterogeneous multiphase ligand substitution reactions at the solid-liquid interface.

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