Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 57, Issue 3, Pages 693-697Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201710277
Keywords
amination; hypervalent iodine; iminoiodanes; photoreactions; alpha-aminoketones
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Funding
- JSPS KAKENHI [16H06384, 17K15423]
- Grants-in-Aid for Scientific Research [17K15423, 16H06384] Funding Source: KAKEN
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N-Acyliminoiodinanes were characterized for the first time by X-ray structural analysis. The ortho-methoxymethyl group and the carbonyl oxygen coordinate to the iodine atom of the iminoiodinane. Activation of the N-acyliminoiodinane was achieved by photoirradiation at 370 nm, thereby enabling reaction with various silyl enol ethers to give alpha-aminoketone derivatives in good to high yield. N-sulfonyliminoiodinanes bearing ortho substituents were used in photoinduced amination.
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