Journal
ACS APPLIED MATERIALS & INTERFACES
Volume 10, Issue 1, Pages 1250-1257Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acsami.7b16711
Keywords
MOFs; epoxy nanocomposites; ZIF-8; curing agents; low-k dielectrics
Funding
- KANEKA Corporation
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Zeolitic imidazole framework-8 (ZIF-8) is utilized as a functional filler and a curing agent in the preparation of epoxy nanocomposites. The imidazole group on the surface of the ZIF-8 initiates epoxy curing, resulting in covalent bonding between the ZIF-8 crystals and epoxy matrix. A substantial reduction in dielectric constant and increase in tensile modulus were observed. The implication of the present study for utilization of metal organic framework to improve physical and mechanical properties of polymeric matrixes is discussed.
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