Application of Inductively Coupled Plasma-Atomic Emission Spectrometry/Mass Spectrometry to Phase Analysis of Gold in Gold Ores

Inductively coupled plasma-atomic emission spectrometry/mass spectrometry (ICP-AES/MS) is a potentially powerful tool in chemical phase analysis of gold in batch mode, especially applicable to the low-grade gold ores with gold content of far below detection limit of the other methods, but it has not been used in gold phase analysis of gold ores. In this work, three types of typical gold deposits (altered rock type, quartz vein type, and microscopic disseminated type) and national standard reference materials of gold ores were used to establish and validate a method for gold phase analysis of gold ores using ICP-AES/MS. The optimum conditions of phase analysis were determined, including the sample granularity and preparation procedures, separation absorbent, pretreatment procedures of various phases of gold and optimized instrument parameters. Evaluation of the optimized method showed that this method had acceptable precision (RSD: 1.1%-10.6%) and accuracy (relative error, RE: 0.5%-6.3%), and the detection results of gold in ores were comparable with those obtained using the hydroquinone volumetric method-extraction flame atomic absorption spectrometry (VOL-AAS) and graphite furnace atomic absorption spectrometry (GFAAS) methods. The sum content of gold of the 4 phases (free gold, F-Au; linked gold, L-Au; sulphide-bearing gold, S-Au; and other mineral-bearing gold, A(Au)) conformed to the total gold content and was consistent with the results of rock-mineral identification. The proposed method had a low detection limit (0.30 ng g(-1)) and wide linear range (5.0 ng mL(-1)-20.00 mu g mL(-1)). It is a simple, rapid, and efficient method for gold phase analysis in batch form.