Journal
ACS APPLIED ENERGY MATERIALS
Volume 1, Issue 2, Pages 312-318Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acsaem.7b00242
Keywords
Sn4Ni3 nanoparticles; long-term cycling stability; template-free electrodeposition; anode material; lithium-ion battery
Funding
- Shenzhen Science and Technology Research Grant [JCYJ20160531141109132, JCYJ20170412150450297]
- National Natural Science Foundation of China [21622407, 21404009]
- Guangdong Innovative and Entrepreneurial Research Team Progress [2013N080]
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The key challenge in utilizing tin-based intermetallic compounds for lithium-ion batteries (LIBs) is the poor cycling stability which is caused by the huge volume change during the alloying/de-alloying processes. In this work, concerning this issue, a novel template-free electrodeposition procedure to prepare mutual independent Sn4Ni3 nanoparticles is presented. As-fabricated Sn4Ni3 nanoparticles deliver a high reversible capacity of 388.9 mAh g(-1) at a current density of 50 mA g(-1). Especially, such materials possess admirable cycling stability (no capacity fading after 1200 cycles at 200 mA g(-1)) which can be attributed to the mutual independence of each nanoparticle. Combining with the high rate capability, the Sn4Ni3 nanoparticles present a promising future of long-life tin-based intermetallic LIB anodes.
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