Journal
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY B
Volume 11, Issue 3, Pages 460-465Publisher
MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S1990793117030137
Keywords
laser initiation; PETN; metal nanoparticles; chemiluminescence; nitrogen dioxide; spectrokinetic characteristics of explosion; photochronograph; polychromator
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Spectrokinetic characteristics of light emission from PETN-based composites containing metal (aluminum, nickel, or iron) nanoparticle inclusions are reported. These characteristics have been measured online using a spectrophotochronograph during the action of a laser pulse (1064 nm, 14 ns). As the PETNbased composites are laser-irradiated, the chemical reaction causing the explosive decomposition of the sample begins during the action of the laser pulse. The observed light emission in the 350-750 nm spectral range can be classified as chemiluminescence.
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