Journal
RUSSIAN JOURNAL OF ELECTROCHEMISTRY
Volume 53, Issue 10, Pages 1182-1188Publisher
MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S1023193517100123
Keywords
Green's function; electron transfer; adiabaticity; propagator; Levich-Dogonadze theory; electrochemical charge transfer
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We present a model Hamiltonian for electrochemical electron transfer, and use Green's functions as the starting point for three different approaches to the calculation of rate constants: first order perturbation theory, which is equivalent to the Levich and Dogonadze theory, the calculation of adiabatic free energy surfaces, and propagation in time. We discuss the similarities and differences between these methods.
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